Preparation of nickel- based catalysts by Ca 2+, Mg2+ exchange in MCM- 41
for methanation of synthesis gas pr operties exploration
Author information+
(School of Chemical Engineering and Technology, Shihezi University/Key Engineering of Xinjiang Bingtuan- Province of State
Key Laboratrory Cultivation Base Construction, Xinjiang, Shihezi 832003,China)
Preparation of natural gas by coal is in line with the development requirements of clean utilization of coal, which is
a key step for methanation of synthesis gas, and synthesis gas methanation catalysts is the core of the key. In order to explore
efficient and stable synthesis gas methanation catalyst, we prepared nickel- based catalysts with the excess impregnation method,
and used ion exchange technique to add alkaline earth metal Ca2+, Mg2+ into the MCM- 41 to explore the effect on the catalyst
activity. In the n (H2)∶n(CO)=3∶1, under a reaction pressure of 1.5 MPa, 350 ℃ of the reaction temperature and WHSV=30000
h- 1 reaction conditions, CO conversion of an alkaline earth modified Ni/MgO- MCM- 41 catalyst is 99%, and selectivity of the
catalyst reaches 90.4%. At 250 ℃, alkaline earth modified catalysts exhibit good low- temperature activity and is higher than
that of Ni/MCM- 41 by 60%. And alkaline earth modified catalysts have stability of activity at high temperature at 550 ℃
under no obvious decline in activity tests. After a series of characterization and analysis, we know that the fine particles of the
nickel distribute on surface of the carrier, and the carrier has a strong interaction with nickel particles and alkaline additives
Ca2+, Mg2+ prevents nickel particles from sintering
WEN Bo, ZHU Mingyuan, DAI Bin.
Preparation of nickel- based catalysts by Ca 2+, Mg2+ exchange in MCM- 41
for methanation of synthesis gas pr operties exploration. Journal of Shihezi University. 2016, 34(3): 360-366 https://doi.org/10.13880/j.cnki.65- 1174/n.2016.03.017
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] Park J，Dong J H，Park J S.Hydrogen utilization as a fuel:
hydrogen-blending effects in flame structure and NO emission behaviour of CH4-air flame [J].International Journal
of Energy Research，2007，31(5):472-485.
[2] 中国能源年鉴编辑委员会.2005 中国能源年鉴[M].北京:
北京科学技术出版社，2007:47-49.
[3] 陈贵锋，俞珠峰，成玉琪.中国煤炭加工技术发展的思考
[J].洁净煤技术，2001，7(1):9-13.
Chen G F，Yu Z F，Cheng Y Q.Ponderation of Coal Processing Technology Development in China[J].Clean Coal Technology，2001，7(1):9-13.
[4] 谷天野.煤炭洁净加工与高效利用[J].洁净煤技术，2006，12
(4):88-90.
Gu T Y.Coal Clean Processing and Efficiency Utilization.
Clean Coal Technology[J]，2006，12(4):88-90.
[5] Hwang S，Lee J，Hong U G，Seo J G，Jung J C，Koh D J，
Lim H，Byun C，Song I K.Methane production from carbon
monoxide and hydrogen over nickel-alumina xerogel catalyst:effect of nickel content[J].Journal of Industrial and Engineering Chemistry，2011，17(1):154-157.
[6] Xavier K O，Sreekala R，Rashid K K A，Yusuff K K M，
Sen B.Doping effects of cerium oxide on Ni/Al2O3 catalysts
for methanation[J].Catalysis Today，1999，49:17-21.
[7] Derekaya F B，Yasar G.The CO methanation over NaYzeolite supported Ni/Co3O4，Ni/ZrO2，Co3O4/ZrO2 and Ni/Co3O4/
ZrO2 catalysts[J].Catalysis Communications，2011，13:73-77.
[8] Panagiololopulou P，Kondaridcs D I，Verykios X E.Selective
methanation of CO over supported Ru catalysts [J].Applied
Catalysis B:Environmental，2009，88:470-478.
[9] Sabatier P，Senderens J B.Hydrogenation of CO overnickel
to produce methane [J].Bulletin of the Chemical Society of
Japan，1902，21:504-506.
[10] Liu H Z，Zou X J，Wang X G，et al.Effect of CeO2 addition
on Ni/Al2O3 catalysts for methanation of carbon dioxide
with hydrogen [J].Journal of Natural Gas Chemistry，2012,21:
703-707.
[11] Wu R，Ghang Y，Wang Y，et al.Effect of ZrO2 promoter on
the catalytic activity for CO methanation and adsorption
performance of the Ni/SiO2 catalyst[J].Journal of Fuel Chemistry and Technology，2009，37(5):578-582[12] Gao J，Jia C，Li J，Gu F，Xu G，Zhong Z，Su F.Nickel catalysts supported on barium hexaaluminate for enhanced CO
methanation[J].Industrial & Engineering Chemistry Research,
2012，51:10345-10353.
[13] Yu Y，Jin G，Wang Y，Guo X.Synthetic natural gas from CO
hydrogenation over silicon carbide supported nickel catalysts[J].Fuel Processing Technology，2011，92:2293-2298.
[14] Kramer M，Stowe K，Duisberg M，Muller F，Reiser M，Sticher
S，Maier W F.The impact of dopants on the activity and
selectivity of a Ni-based metanation catalyst [J].Applied
Catalysis A:General，2009，369:42-52.
[15] 王承学，龚杰.二氧化碳加氢甲烷化镍锰基催化剂的研究
[J].天然气化工，2011，36:4-6.
Wang C X，Gong J.Study on Ni-Mo-based catalysts for
mathanation of carbon dioxide[J].Natural Cas Chemical Industry，2011，36:4-6.
[16] 马胜利，谭猗生，张清德，韩台卓.不同形貌 Ni/γ-Al2O3 催
化剂催化 CO 甲烷化反应的研究[J].燃料化学学报，2011，
39:224-228.
Ma S L，Tan Q S，Zhang Q D，Han Y Z.CO methanation
over Ni/γ-A12O3 catalysts with different morphologies [J].
Journal of Fuel Chemistry and Technology，2011，39:224-
228.
[17] 张加赢，辛忠，孟鑫，陶淼.基于 MCM-41 的镍基甲烷化催
化剂活性与稳定性[J].化工学报，2013，65:160-168.
Zhang J Y，Xin Z，Meng X，Tao M.Activity and stability of
nickel based MCM-41 methanation catalysts for production
of synthetic natural gas[J].CIESC Journal，2013，65:160-168.
[18] 谭静，王乃继，肖翠微.煤制天然气镍基催化剂的研究进
展[J].洁净煤技术，2011，17(2):43-45，53.
Tan J，Wang N J，Xiao C W.The research progress of coal
gas nickel-based catalysts[J].Clean Coal Technology，2011，
17(2):43-45，53.
[19] 王琴琴，朱明远，代斌.Au- 基催化剂的制备及其在乙炔氢
氯化反应中的催化活性[J].石河子大学学报:自然科学版，
2015，33(1):1-6.
Wang Q Q，Zhu M Y，Dai B.Preparation of Au-based catalyst and its catalytic activity in acetylene hydrochlorination[J].Journal of Shihezi University:Natural Science，2015，
33(1):1-6.
PDF(5722 KB)
